- Thấy Cu không phản ứng với HCl .

\(\Rightarrow m_{cr}=m_{Cu}=6,4\left(g\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

.x.......................................1,5x.........

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

.y....................................y.............

Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}27x+56y+6,4=17,4\\1,5x+y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\) ( mol )

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=5,4\\m_{Fe}=5,6\end{matrix}\right.\) ( g )

b, \(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

.......0,1.........0,2...............................

\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)

...0,2.......0,6..........................

\(\Rightarrow n_{NaOH}=0,2+0,6=0,8< 1\)

=> Trong B còn có HCl dư .

\(NaOH+HCl\rightarrow NaCl+H_2O\)

...0,2..........0,2....................

=> Dư 0,2 mol HCl .

\(\Rightarrow n_{HCl}=2n_{H_2}+0,2=1\left(mol\right)\)

\(\Rightarrow m_{ddB}=17,4+250-6,4-0,8=260,2\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,2.36,5}{260,2}.100\%\approx2,8\%\\C\%_{FeCl_2}\approx4,88\%\\C\%_{AlCl_3}\approx10,26\%\end{matrix}\right.\)

Vậy ....

gồm A???

\(n_{khi}=n_{H2}=\frac{11,2}{22,4}=0,5\left(mol\right)\)

Gọi số mol Mg, Fe, Cu là a, b, c

Ta có \(24a+56b+64c=28\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(n_{H2}=n_{Mg}+n_{Fe}=a+b=0,5\)

Cu không phản ứng

\(\rightarrow64c=9,6\)

\(\rightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\\c=0,15\end{matrix}\right.\)

Cho tác dụng với NaOH

\(HCl+NaOH\rightarrow NaCl+H_2O\)

\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

0,3 _______________0,3_______________

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

0,2 ________________0,2_______________

\(Mg\left(OH\right)_2\rightarrow MgO+H_2O\)

0,3___________0,3_______

\(Fe\left(OH\right)_2\rightarrow FeO+H_2O\)

0,2__________0,2_______

\(\rightarrow m=0,3.40+0,2.72=26,4\left(g\right)\)

\(n_{HCl}=0,3.1=0,3mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

0,1        0,3                        0,15  ( mol )

\(m_{Al}=0,1.27=2,7g\)

\(\Rightarrow m_{Al}=9,1.2,7=6,4g\)

\(V_{H_2}=0,15.22,4=3,36l\)

nHCl = 0,3 . 1 = 0,3 (mol)

PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2

Mol: 0,1 <--- 0,3 ---> 0,1 ---> 0,15

mAl = 0,1 . 27 = 2,7 (g(

mCu = 9,1 - 2,7 = 6,4 (g)

VH2 = 0,15 . 22,4 = 3,36 (l)

a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Theo PT: \(n_{Fe}=n_{H_2}=0,25\left(mol\right)\)

\(\Rightarrow m_{Fe}=0,25.56=14\left(g\right)\)

m_Cu = 20,4 - 14 = 6,4 (g)

b, \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{14}{20,4}.100\%\approx68,63\%\\\%m_{Cu}\approx31,37\%\end{matrix}\right.\)

c, Theo PT: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,5.36,5}{200}.100\%=9,125\%\)